Synthesis of new fullerene C<sub>121</sub> by neutron irradiation

CHEN Zhenling QU Li CHENG Yue XING Gengmei YUAN Hui ZHAO Yuliang CHAI Zhifang

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Synthesis of new fullerene C₁₂₁ by neutron irradiation

更新时间：2021-03-12

- Synthesis of new fullerene C₁₂₁ by neutron irradiation
- NUCLEAR TECHNIQUES Issue 2, (2005)
- 作者机构：
  
  1. 中国科学院高能物理所核分析重点实验室
  2. 中国科学院高能物理所核分析重点实验室,北京,100049
- 作者简介：
- 基金信息：
  
  国家自然科学基金项目( 10490180 );中国科学院和中国科学院高能物理所核分析开放实验室项目资助
- DOI：
  CLC： O571.5
- Published：01 February 2005
- 稿件说明：
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[1]陈振玲,屈力,程悦,邢更妹,袁慧,赵宇亮,柴之芳.中子照射法合成新型富勒烯C_(121)[J].核技术,2005(02):101-104.

CHEN Zhenling QU Li CHENG Yue XING Gengmei YUAN Hui ZHAO Yuliang CHAI Zhifang. Synthesis of new fullerene C₁₂₁ by neutron irradiation[J]. Nuclear techniques, 2005, (2): 101-104.
[1]陈振玲,屈力,程悦,邢更妹,袁慧,赵宇亮,柴之芳.中子照射法合成新型富勒烯C_(121)[J].核技术,2005(02):101-104. DOI：

CHEN Zhenling QU Li CHENG Yue XING Gengmei YUAN Hui ZHAO Yuliang CHAI Zhifang. Synthesis of new fullerene C₁₂₁ by neutron irradiation[J]. Nuclear techniques, 2005, (2): 101-104. DOI：

摘要

利用反应堆中子照射富勒烯混合物 C60合成了新型 C121的三个同分异构体。实验结果表明较低的热快中子注量比率、原料照射前适当的氧化处理和较长的中子照射时间有利于 C121 的形成。此研究首次合成了 C121的三种同分异构体并且拓展了核技术的应用领域。

Abstract

The synthesis of three new isomers of C121 by neutron irradiation of C60 is reported in this paper. The re- sults indicate that lower flux ratio of thermal to fast neutrons

proper oxidation of C60

and longer irradiation time are advantageous to the formation of C121. This new nuclear method

by which three isomers of C121 were prepared for the first time

has opened a new way to synthesize other odd-numbered large carbon fullerene.

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Synthesis of new fullerene C121 by neutron irradiation

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摘要

Abstract

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Synthesis of new fullerene C₁₂₁ by neutron irradiation