Study on Ar ion bombardment induced surface structural   and compositional changes in PET

LIU Changlong  ZHU Zhiyong  JIN Yunfan  SUN Youmei  HOU Mingdong  WANG Yanbin    WANG Zhiguang  CHEN Xiaoxi  LIU Jie  ZHANG Chonghong  LI Baoquan

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Study on Ar ion bombardment induced surface structural and compositional changes in PET

更新时间：2021-03-12

- Study on Ar ion bombardment induced surface structural and compositional changes in PET
- NUCLEAR TECHNIQUES Issue 4, (2001)
- 作者机构：
  
  1. 中国科学院近代物理研究所,兰州,730000
  2. 中
- 作者简介：
- 基金信息：
  
  国家自然科学基金 !(19775 0 5 8);中国科学院“九五”重点基金 !(KJ 95 2 -S1- 42 3);西部之光基金资助
- DOI：
  CLC： O641
- Published：01 April 2001
- 稿件说明：
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[1]刘昌龙,朱智勇,金运范,孙友梅,侯明东,王衍斌,王志光,陈晓曦,刘杰,张崇宏,李保权.Ar离子辐照PET膜引起的表面结构和组分变化研究[J].核技术,2001(04):288-294.

LIU Changlong ZHU Zhiyong JIN Yunfan SUN Youmei HOU Mingdong WANG Yanbin WANG Zhiguang CHEN Xiaoxi LIU Jie ZHANG Chonghong LI Baoquan. Study on Ar ion bombardment induced surface structural and compositional changes in PET[J]. Nuclear techniques, 2001, (4): 288-294.
[1]刘昌龙,朱智勇,金运范,孙友梅,侯明东,王衍斌,王志光,陈晓曦,刘杰,张崇宏,李保权.Ar离子辐照PET膜引起的表面结构和组分变化研究[J].核技术,2001(04):288-294. DOI：

LIU Changlong ZHU Zhiyong JIN Yunfan SUN Youmei HOU Mingdong WANG Yanbin WANG Zhiguang CHEN Xiaoxi LIU Jie ZHANG Chonghong LI Baoquan. Study on Ar ion bombardment induced surface structural and compositional changes in PET[J]. Nuclear techniques, 2001, (4): 288-294. DOI：

摘要

用 35MeV u的Ar离子室温下辐照多层堆叠的半晶质的聚酯（PET）膜

采用X射线衍射技术和X射线光电子谱仪分析研究了辐照引起的表面结构和组分的变化。结果表明

Ar离子辐照PET膜引起了明显的非晶化转变和化学键断裂

断键主要发生在甲氧基和羰基功能团上

并使这两个功能团中的C和O的比分相对减少。非晶化效应和化学键断裂同时依赖于离子的照射剂量和离子在样品表面的电子能量损失

剂量越高

表面电子能量损失越大

效应就明显。同时定性地讨论了结果

Abstract

Semicrystalline polyethylene terephthalate (PET) film stacks were irradiated at room temperature with 35MeV/u Ar ions. Ion beam induced structural and compositional modifications were studied by means of X-ray diffractometer (XRD) and X-ray photoelectron spectroscopy (XPS) techniques. Significant amorphous transformation and chemical chain scissions were observed

which depended strongly on ion fluence and electronic energy loss near the sample surface. The chemical chain scissions were mainly found at carbonyl and methoxyl groups

which led to the relative decrease of amount of carbon and oxygen in these functional groups. The effects of amorphization and bond breaking increased with increase of ion fluence and electronic energy loss. The results were qualitatively discussed.

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Surface modifications of PET induced by high energy Ar ion irradiation

^The latent track etching of PET films irradiated by 40 Ar ions

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金运范

李保权

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